Types of Chemical Bonds

Chemical bonds are the forces that hold atoms together to form molecules and compounds. Atoms bond to achieve lower energy and greater stability.

1. Ionic Bond

An ionic bond is formed when one atom completely transfers one or more electrons to another atom, forming oppositely charged ions that attract each other.

How it forms

  • Occurs between a metal and a non-metal
  • Metal loses electrons → becomes a cation (+)
  • Non-metal gains electrons → becomes an anion (−)
  • Electrostatic attraction holds ions together

Example

Sodium Chloride (NaCl)

Na → Na⁺ + e⁻
Cl + e⁻ → Cl⁻

Properties

Melting pointHigh
Electrical conductivityYes (molten / aqueous)
SolubilityOften soluble in water
Bond strengthStrong

2. Covalent Bond

A covalent bond is formed when two atoms share one or more pairs of electrons to achieve stability.

How it forms

  • Occurs between non-metal atoms
  • Electrons are shared, not transferred
  • Bond is directional
  • Forms molecules

Examples

  • H₂O — Water
  • CO₂ — Carbon dioxide
  • O₂ — Oxygen

Types of Covalent Bonds

TypeElectron PairsExample
Single1H–H
Double2O=O
Triple3N≡N

Polar vs Non-Polar

  • Polar: Unequal sharing (H₂O)
  • Non-polar: Equal sharing (O₂, N₂)

3. Metallic Bond

A metallic bond is formed when positive metal ions are surrounded by a sea of delocalized electrons.

Electron Sea Model

  • Valence electrons are free to move
  • Explains electrical conductivity
  • Non-directional bond

Examples

  • Iron (Fe)
  • Copper (Cu)
  • Aluminium (Al)

Properties

ConductivityHigh
MalleabilityHigh
DuctilityHigh

Comparison of Chemical Bonds

PropertyIonicCovalentMetallic
Electron behaviorTransferredSharedDelocalized
ConductivityHigh (solution)LowHigh
Melting pointHighLowVariable

Dot–Cross Diagrams

Dot–cross diagrams show the transfer or sharing of electrons using different symbols for different atoms.

Na •  → Na⁺ Cl ××××××× + • → Cl⁻ H • : O : • H

Electronegativity Difference Simulator

ΔEN = 1.5
Polar Covalent Bond

3D Bond Models

Visual representations to support theoretical understanding of chemical bonds

Ionic Bond

Electron transfer forms oppositely charged ions

Example: NaCl

Covalent Bond

Shared electron pair holds atoms together

Example: H₂, O₂

Metallic Bond

Delocalized electrons enable conductivity

Example: Cu, Fe